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When preparing a mocha chiller with decaf coffee, the type of milk you choose should align with the overall richness and texture that complements the flavors of the mocha. Whole milk is known for its creamy consistency and full-bodied flavor, which enhances the drink's indulgence and balances the chocolate element in the mocha.

Whole milk is often favored in coffee beverages for its ability to create a smooth mouthfeel and blend well with espresso, providing a satisfying experience. Using whole milk in this case will preserve the intended taste and consistency of the mocha chiller, making it a preferable choice.

Other milk options, such as skim, almond, or oat milk, while they may be suitable for certain dietary restrictions or preferences, tend to have different flavor profiles or textures that could compromise the richness typically associated with a traditional mocha.